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Climate-Relevant Isoprene Chemical Pathways Uncovered
Published: April 06, 2009
Posted: April 17, 2009

In spite of their many positive attributes, including removing carbon from the atmosphere, some trees also contribute to the challenges of climate change. Many deciduous trees emit isoprene (2-methyl-1,3-butadiene, C5H8) during daylight hours, a major organic carbon compoundĀ  accounting for up to 2% of the carbon fixed by those plants and about one third of total volatile organic compounds (VOC) emissions. DOE research has previously demonstrated that isoprene oxidation may contribute significantly to the global aerosol burden with impacts on climate forcing and ozone production. A recent study by this same group described isoprene photooxidation and developed a detailed mechanism, including branching ratios and yields, for the compounds identified. The authors summarize the most important features of this mechanism in a scheme appropriate for use in global chemical transport models. The impact of this chemistry is important in the light of the potential for significant changes in isoprene emissions caused by climate changeĀ  and changes in land use.

Reference: F. Paulot, J. D. Crounse, H. G. Kjaergaard, J. H. Kroll, J. H. Seinfeld, and P. O. Wennberg (2009), Isoprene photooxidation: new insights into the production of acids and organic nitrates, Atmos. Chem. Phys., 9, 1479-1501.

Contact: Ashley Williamson, SC-23.1, (301) 903-3120
Topic Areas:

  • Research Area: Earth and Environmental Systems Modeling
  • Research Area: Atmospheric System Research
  • Research Area: Terrestrial Ecosystem Science

Division: SC-33.1 Earth and Environmental Sciences Division, BER


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